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. 2017 Jun 27;56(14):8147–8158. doi: 10.1021/acs.inorgchem.7b00852

Figure 3.

Figure 3

(A) Experimental Fe L2,3-edge X-ray absorption spectra of [FeIII(SDur)4]− (red) and [FeII(SPh)4]2– (black) complexes. (B, C) Experimental Fe L2,3-edge X-ray absorption spectra at 6 T magnetic field with circularly right (solid line) and circularly left (dashed line) polarized light for [FeIII(SDur)4]− (red, B) and [FeII(SPh)4]2– (black, C) complexes. (D) Experimental Fe XMCD spectra of [FeIII(SDur)4]− (red) and [FeII(SPh)4]2– (black) complexes. The blue arrow in (A) indicates the shift between the maxima of the L3-edge peaks for these complexes.