. 2017 Jul 9;56(28):3531–3538. doi: 10.1021/acs.biochem.7b00432

Table 2. Rate Constants for Ru-Sensitizer Quenching (γ₁), Heme Reduction (γ₂), and Heme Oxidation (γ₃) Extracted from Global Fitting of Transient Absorption Data.

enzyme	γ₁ (s^–1)	γ₂ (s^–1)	γ₃ (s^–1)
Ru_C97(CYP102A1)W96	1.6 × 10⁷	3.6 × 10⁴	1.1 × 10²
Ru_C97(CYP102A1)W96H	1.6 × 10⁷	6.0 × 10⁴	1.9 × 10²
Ru_C77(CYP119)H76	1.9 × 10⁷	5.7 × 10⁴	1.4 × 10²
Ru_C77(CYP119)H76W	1.9 × 10⁷	8.1 × 10⁴	1.3 × 10²

Table 2. Rate Constants for Ru-Sensitizer Quenching (γ1), Heme Reduction (γ2), and Heme Oxidation (γ3) Extracted from Global Fitting of Transient Absorption Data.