Table 1. Averaged Values of the Different Nanoparticle “Batches” For the Charge Transfer Coefficient (α) Determined from Simulation and the Standard Heterogeneous Electron Transfer Rate Constant (k°)^a.

	α (simulation)	k° (cm/s)
5 nm Au	0.540 ± 0.020	8.75 ± 3.7 (10−5)
12 nm Au	0.477 ± 0.015	9.64 ± 5.5 (10−6)
50 nm Au	0.501 ± 0.015	7.08 ± 4.2 (10−6)
4 nm Pt	0.742 ± 0.006	8.71 ± 2.0 (10−2)
10 nm Ptb	0.775 ± 0.003	7.66 ± 0.88 (10−2)
30 nm Pt	0.758 ± 0.007	4.23 ± 0.62 (10−2)

^aReproduced with permission ref 46. Copyright 2016 American Chemical Society.

^bCubic nanoparticles capped with polyacrylate.