Table 1.
Position | 1a δH (J in Hz) | 2a δH (J in Hz) |
---|---|---|
4 | 7.22 d (8.4) | 7.33 d (8.4) |
5 | 6.61 dd (8.4, 2.3) | 6.65 dd (8.4, 2.4) |
7 | 7.34 (broadening) | 7.35 d (2.4) |
11α | 2.45 ddd (12.0, 9.2, 5.2) | 2.69 dt (6.5, 12.0) |
11β | 2.83 dd (9.2, 7.2) | 3.42 dd (12.0, 8.9) |
12α | 1.92 dd (12.0, 5.2) | 2.31 dd (12.0, 6.5) |
12β | 2.04 dt (7.2, 12.0) | 2.13 dt (8.9, 12.0) |
2-CH3 | 1.47 s | 1.75 s |
3-OH | 5.50, br.s | 5.81, br.s |
6-OCH3 | 3.72 s | 3.74 s |
13-OCH3 | 3.77 s | 3.75 s |
14-OCH3 | 3.53 s |
Run at 400 MHz, DMSO-d6.