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. Author manuscript; available in PMC: 2017 Aug 26.
Published in final edited form as: Angew Chem Int Ed Engl. 2016 Aug 1;55(36):10578–10599. doi: 10.1002/anie.201600791

Scheme 33.

Scheme 33

Rationale for the regioselectivity of electron-rich alkenes in Rh(III)-catalyzed C(sp2)–H olefination using the N-pivaloyoxy amide directing group (Marsden et al., 2014).[49]