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. Author manuscript; available in PMC: 2017 Aug 26.
Published in final edited form as: Angew Chem Int Ed Engl. 2016 Aug 1;55(36):10578–10599. doi: 10.1002/anie.201600791

Scheme 5.

Scheme 5

Pd(II)-catalyzed C(sp2)–H amidation and C(sp3)–H chlorination via Pd(II)/Pd(0) catalysis using the N-methoxy amide directing group (Yu et al., 2008).[16] DCE = 1,2-dichloroethane.