. 2017 Apr 24;121(21):4139–4151. doi: 10.1021/acs.jpca.7b00076

Table 3. Metal–Carbon Distance and the Average of the Three Closest Metal–Deuterium Distances for the Methane Molecule Adsorbed at the Metal Site from the M₂(dobdc)·1.5CD₄ Structures Measured at 8 K.

metal	Mg	Mn	Fe	Co	Ni	Cu	Zn
M–C (Å)	2.95(2)	2.93(3)	2.90(3)	2.95(3)	2.95(1)	3.28(1)	3.09(1)
M–D avg (Å)	2.79(3)	2.77(5)	2.78(4)	2.80(5)	2.79(2)	3.10(2)	2.92(3)

Table 3. Metal–Carbon Distance and the Average of the Three Closest Metal–Deuterium Distances for the Methane Molecule Adsorbed at the Metal Site from the M2(dobdc)·1.5CD4 Structures Measured at 8 K.