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. Author manuscript; available in PMC: 2018 Jun 1.
Published in final edited form as: Arch Biochem Biophys. 2017 May 10;623-624:9–19. doi: 10.1016/j.abb.2017.05.004

Scheme 11.

Scheme 11

The Required Rate of Chemistry in the Reaction of αY60W-CaaD and 10, where S corresponds to 10, P corresponds to bromide, and R corresponds to the reactive species that forms a covalent bond with enzyme.