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. Author manuscript; available in PMC: 2018 Mar 1.
Published in final edited form as: J Am Chem Soc. 2017 Feb 14;139(8):3186–3195. doi: 10.1021/jacs.6b12990

Figure 3.

Figure 3

Top: SPMeAN X-ray structure and its geometric and spectroscopic features. Middle: Molecular orbital diagrams of the SPMeAN core that lead to lengthening of the O–O bond without concomitant O–O cleavage. Bottom: Subjects of this report: coordination of phenolates and Lewis acids to SPMeAN imparts tyrosinase-like hydroxylation and pMMO-like C–H oxidation reactivity through OMeAN.