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. Author manuscript; available in PMC: 2018 Jun 2.
Published in final edited form as: Org Lett. 2017 May 17;19(11):2837–2840. doi: 10.1021/acs.orglett.7b01009

Scheme 1.

Scheme 1

Inverse Klemer-Rodemeyer Fragmentation of 2,3-O-Benzylidinerhamnose Derivative 8 (a) and Preparation of Ascaroside Derivatives via Methoxyrhamnose-Derived Cyclic Sulfates (b, c)