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. Author manuscript; available in PMC: 2018 Jan 2.
Published in final edited form as: Angew Chem Int Ed Engl. 2016 Dec 1;56(1):297–301. doi: 10.1002/anie.201607611

Scheme 1.

Scheme 1

Generation and self-decay of the heterodinuclear [NiIII(μ-O)2CoIII]2+ complex 2 and it’s homodinuclear [MIII(μ-O)2MIII]2+ analogues 3 and 4 (M = Ni, Co). Inset: The structure of the previously reported[3] asymmetric bis(μ-oxido)NiIIICuIII compound with nucleophilic oxido ligands.