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Zn(II)->Cu(I) replacement reaction on the Zn9-LlwtMT, Zn6-Lltr1MT, and Zn6-Lltr2MT complexes. (A) CD spectra of a 10 μM solution of the Zn-LlMT samples, titrated with a Cu(I) solution at neutral pH; (B) Comparison of the CD spectra (normalized) of the three recombinant productions of Cu-LlMT with those obtained from the in vitro metal displacement reactions.
