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. 2017 Jul 6;18(7):1452. doi: 10.3390/ijms18071452

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© 2017 by the authors.

Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).

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Zn(II)->Cu(I) replacement reaction on the Zn₉-LlwtMT, Zn₆-Lltr1MT, and Zn₆-Lltr2MT complexes. Deconvoluted ESI-MS recorded, at pH 7.0 and 2.4, after the addition of 2, 4, 6, 8, and 12 equivalents of Cu(I) to the recombinant Zn-LlMT preparations.