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. Author manuscript; available in PMC: 2018 Mar 1.
Published in final edited form as: J Am Chem Soc. 2017 Feb 16;139(8):3153–3160. doi: 10.1021/jacs.6b12663

Table 4.

Conjunctive coupling between Grignard-derived boron "ate" complexes and organotriflates.a

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(a)

Conjunctive coupling was conducted at 0.17 M. Yields represent isolated yields of purified material. Both the yield and the enantiomer ratio (er) represent the average value for two experiments.

(b)

Product isolated as the derived alcohol.

(c)

Reaction conducted at 60 °C.

(d)

Solvent = THF.