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. 2005 Feb 17;24(5):919–928. doi: 10.1038/sj.emboj.7600585

Table 2.

Closest contacts between chlorophylls and carotenoids

Chl in (Kühlbrandt et al, 1994) Chl in (Liu et al, 2004) New nomenclature Closest carotenoids Closest π–π contact (Å) (internuclear distance) Mg2+ ligand H bond to Chl b formyl group
Chlorophylls a            
a1 610 Chl 1 Lut 1 3.3 Glu180 Oɛ2  
a2 612 Chl 2 Lut 1 3.5 Asn183 Oδ1  
a3 613 Chl 3 Lut 1 5.0 Gln197 Oɛ1  
a4 602 Chl 4 Lut 2 3.2 Glu65 Oɛ2  
a5 603 Chl 5 Lut 2 3.6 His68 Nɛ2  
a6 604 Chl 6 Lut 2 4.8 Wat-Gly78 O  
b2 611 Chl 7 Lut 1 9.1 PG O4  
b3 614 Chl 8 Lut 1 8.0 His212 Nɛ2  
             
Chlorophylls b            
601 Chl 9 Lut 2 8.0 Tyr24 O
a7 607 Chl 10 Lut 2 5.1 Wat-Chl 13 OMC Gln131 Nɛ1
b1 608 Chl 11 Neo 4.3 Wat-Val138 O Leu148 N
b5 609 Chl 12 Lut 2 7.8 Glu139 Oɛ2 Gln131 Nɛ1
b6 606 Chl 13 Lut 2 4.9 Wat-Gln131 Oɛ2 Wat-Chl 10 Mg
605 Chl 14 Neo 12.3 Val119 O Ser123 N