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. 2017 Apr;23(15):2276–2286. doi: 10.2174/1381612822666161201150131

Table 3.

Some electronic constants of the substituents in the compounds 6-24.

Compound Substituent σm σp F R
6 H - - - -
7 o-Cl - - 0.41 -0.15
8 m-Cl 0.37 - 0.41 -0.15
9 p-Cl - 0.23 0.41 -0.15
10 o,p-DiCl - 0.23 0.41 -0.15
11 o-NO2 - - 0.67 0.16
12 m-NO2 0.71 - 0.67 0.16
13 p-NO2 - 0.78 0.67 0.16
14 o-F - - 0.43 -0.34
15 m-F 0.34 - 0.43 -0.34
16 p-F - 0.06 0.43 -0.34
17 o,p-DiF - 0.06 0.43 -0.34
18 o-CH3 - - -0.04 -0.13
19 m-CH3 -0.07 - -0.04 -0.13
20 p-CH3 - -0.17 -0.04 -0.13
21 o-OCH3 - - 0.26 -0.51
22 m-OCH3 0.12 - 0.26 -0.51
23 p-OCH3 - -0.27 0.26 -0.51
24 o,p-DiOCH3 - -0.27 0.26 -0.51

σm: Hammett substituent constant for meta position; σp: Hammett substituent constant for para position; F: Field effect constant; R: Resonance effect constant