Table 3.
Compound | Substituent | σm | σp | F | R |
---|---|---|---|---|---|
6 | H | - | - | - | - |
7 | o-Cl | - | - | 0.41 | -0.15 |
8 | m-Cl | 0.37 | - | 0.41 | -0.15 |
9 | p-Cl | - | 0.23 | 0.41 | -0.15 |
10 | o,p-DiCl | - | 0.23 | 0.41 | -0.15 |
11 | o-NO2 | - | - | 0.67 | 0.16 |
12 | m-NO2 | 0.71 | - | 0.67 | 0.16 |
13 | p-NO2 | - | 0.78 | 0.67 | 0.16 |
14 | o-F | - | - | 0.43 | -0.34 |
15 | m-F | 0.34 | - | 0.43 | -0.34 |
16 | p-F | - | 0.06 | 0.43 | -0.34 |
17 | o,p-DiF | - | 0.06 | 0.43 | -0.34 |
18 | o-CH3 | - | - | -0.04 | -0.13 |
19 | m-CH3 | -0.07 | - | -0.04 | -0.13 |
20 | p-CH3 | - | -0.17 | -0.04 | -0.13 |
21 | o-OCH3 | - | - | 0.26 | -0.51 |
22 | m-OCH3 | 0.12 | - | 0.26 | -0.51 |
23 | p-OCH3 | - | -0.27 | 0.26 | -0.51 |
24 | o,p-DiOCH3 | - | -0.27 | 0.26 | -0.51 |
σm: Hammett substituent constant for meta position; σp: Hammett substituent constant for para position; F: Field effect constant; R: Resonance effect constant