Table 1.

Glycosylation Reactions

Entry	Acceptor	Product	% Yield, α:β ratio	3JCH (Hz)
1	BnOH	30	96%, α-only	30: 7.2
2	27	31αβ	87%, 6.7:1	31α: 6.4
3	26	32α,β	82%, 4.4:1	32α: 6.9
4	28	33α,β	75%, a4.5:1	33α: 7.2 33β: 0
5	29	34α,β	88%, 34α:34β:35α= 4.7:1:0.9	34α: 7.0
		35		35α: 6,3
6	1-adamantanol	36α,β	73%, 4.2:1	36α: 5.7

^aGlycosylation gave an 84% yield of an inseparable 4.5:1 α:β mixture of the disaccharides, which was saponified to give the products 33α and 33β.