Table 5.
Formulations | Tg (°C) | Tcc (°C) | ΔHcc (J/g) | Tm (°C) | ΔHm (J/g) | Xc (%) | Tc (°C) |
---|---|---|---|---|---|---|---|
1st Heating Scan | Cooling | ||||||
PBS | 41.9 ± 0.2 | 87.4 ± 0.4 | 13.1 ± 2.0 | 114.3 ± 0.1 | 79.9 ± 0.6 | 60.6 ± 2.4 | 79.1 ± 0.6 |
PBS85–ATBC15 | 41.9 ± 1.4 | 87.2 ± 0.2 | 13.8 ± 2.1 | 113.0 ± 0.4 | 77.9 ± 0.6 | 68.3 ± 2.8 | 75.1 ± 0.4 |
PBS80–ATBC20 | 41.5 ± 8.8 | 90.1 ± 0.5 | 11.9 ± 0.7 | 112.8 ± 0.2 | 70.9 ± 2.7 | 66.8 ± 2.3 | 73.0 ± 0.1 |
PBS85–ISE15 | 41.1 ± 0.6 | 88.1 ± 0.9 | 12.5 ± 2.1 | 113.2 ± 0.1 | 75.8 ± 0.2 | 67.3 ± 2.0 | 75.8 ± 0.6 |
PBS80–ISE20 | 41.5 ± 0.3 | 90.6 ± 0.2 | 12.9 ± 1.4 | 111.8 ± 0.1 | 69.7 ± 0.5 | 64.4 ± 2.2 | 74.6 ± 0.1 |
PBS80–ISE30 | 42.5 ± 0.2 | 90.5 ± 0.2 | 11.0 ± 0.3 | 111.8 ± 0.6 | 66.2 ± 1.7 | 71.6 ± 2.6 | 74.1 ± 0.5 |
Tg PLA (°C) | Tm PBS (°C) | Tcc (°C) | Tm1 (°C) | Tm2 (°C) | |||
PLA80–PBS20 | 56.6 ± 0.5 | 113.0 ± 0.4 | 106.6 ± 0.4 | 147.0 ± 0.3 | 153.0 ± 0.3 | ||
(PLA15–ISE15)–PBS20 | 34.3 ± 0.2 | 110.6 ± 0.1 | 79.1 ± 0.1 | 134.6 ± 0.2 | 147.3 ± 0.3 | ||
(PLA80–PBS20)–ISE15 | 32.8 ± 0.4 | 111.0 ± 0.3 | 78.4 ± 0.4 | 134.5 ± 0.4 | 146.8 ± 0.5 | ||
2nd Heating Scan | |||||||
Formulations | Tcc (°C) | ΔHcc (J/g) | Tm (°C) | ΔHm (J/g) | Xc (%) | ||
PBS | 102.3 ± 0.1 | 8.4 ± 0.8 | 113.7 ± 0.3 | 69.5 ± 0.9 | 55.5 ± 0.1 | ||
PBS85–ATBC15 | 97.3 ± 0.3 | 9.4 ± 1.8 | 112.5 ± 0.1 | 70.5 ± 4.2 | 65.2 ± 6.5 | ||
PBS80–ATBC20 | 95.6 ± 0.4 | 9.4 ± 0.5 | 111.8 ± 0.2 | 65.9 ± 5.2 | 64.8 ± 5.3 | ||
PBS85–ISE15 | 98.5 ± 0.4 | 7.3 ± 0.1 | 112.7 ± 0.1 | 71.2 ± 2.7 | 68.1 ± 2.8 | ||
PBS80–ISE20 | 96.4 ± 0.2 | 8.7 ± 0.5 | 111.3 ± 0.1 | 66.6 ± 2.1 | 65.5 ± 3.0 | ||
PBS80–ISE30 | 96.5 ± 0.5 | 9.0 ± 1.0 | 111.2 ± 0.6 | 61.1 ± 3.1 | 67.5 ± 5.5 | ||
Tg PLA (°C) | Tm PBS (°C) | Tcc (°C) | Tm1 (°C) | Tm2 (°C) | |||
PLA80–PBS20 | 55.3 ± 0.4 | 113.1 ± 0.2 | 109.3 ± 0.3 | 147.4 ± 0.4 | 152.9 ± 0.5 | ||
(PLA15–ISE15)–PBS20 | 34.7 ± 0.3 | 111.0 ± 0.1 | 87.1 ± 0.1 | 135.5 ± 0.2 | 147.1 ± 0.4 | ||
(PLA80–PBS20)–ISE15 | 34.7 ± 0.3 | 111.3 ± 0.1 | 87.6 ± 0.4 | 135.5 ± 0.4 | 147.1 ± 0.4 |