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. Author manuscript; available in PMC: 2017 Aug 14.
Published in final edited form as: Chem Rev. 2016 Jun 17;116(14):7818–7853. doi: 10.1021/acs.chemrev.6b00024

Figure 39.

Figure 39

Proposed mechanism for MarG-catalyzed oxidative cyclization and hydroxylation of (10′S)-10′-hydroxyundecylprodigiosin 320. As for the RedG catalytic mechanism, alternative Fe(V)O(OH) and carbocation intermediates are also possible.