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. Author manuscript; available in PMC: 2017 Aug 14.
Published in final edited form as: Chem Rev. 2016 Jun 17;116(14):7818–7853. doi: 10.1021/acs.chemrev.6b00024

Scheme 31.

Scheme 31

RedG and McpG Catalyze Regio- and Stereodivergent Oxidative Carbocyclizations of Undecylprodigiosin (17) To Form Streptorubin B (22) and Metacycloprodigiosin (20), Respectively