Table 1.
no. | 1a | 2c | 3a | 4a | 8c | 9a | 10a | 11a | 12b |
---|---|---|---|---|---|---|---|---|---|
1 | 173.1, C | 174.9, C | 173.2, C | 171.5, C | 173.4, C | 168.9, C | 169.5, C | 169.2, C | 176.8, C |
2 | 99.0, C | 98.8, C | 98.8, C | 106.4, C | 98.4, C | 100.2, C | 99.0, C | 96.6, C | 96.9, C |
3 | 179.5, C | 180.7, C | 178.9, C | 186.5, C | 180.9, C | 199.0, C | 199.7, C | 180.7, C | 201.2, C |
4 | 40.3, CH | 40.4, CH | 39.9, CH | 40.0, CH | 40.7, CH | 40.5, CH | 42.2, CH | 30.0, CH | 38.1, CH |
5 | 33.7, CH2 | 34.2, CH2 | 33.1, CH2 | 38.3, CH2 | 32.8, CH2 | 40.3, CH2 | 38.4, CH2 | 46.1, CH2 | 47.5, CH2 |
6 | 48.1, CH | 48.1, CH | 47.7, CH | 77.8, C | 48.5, CH | 79.7, C | 45.9, CH | 78.0, C | 210.9, C |
7 | 210.7, C | 210.2, C | 210.5, C | 209.1, C | 209.5, C | 207.2, C | 211.6, C | 215.3, C | 170.2, C |
8 | 58.5, CH | 59.7, CH | 58.5, CH | 66.1, CH | 53.2, CH | 48.3, CH | 34.4, CH2 | 43.9, CH2 | 122.6, CH |
9 | 27.2, CH2 | 27.6, CH2 | 26.8, CH2 | 77.1, CH | 36.2, CH2 | 55.9, CH | 19.4, CH2 | 27.2, CH | 149.8, CH |
10 | 50.3, CH | 49.7, CH | 48.8, CH | 50.6, CH | 60.5, C | 45.9, CH | 44.6, CH | 45.3, CH | 47.8, CH |
11 | 81.3, CH | 80.9, CH | 78.9, CH | 72.2, CH | 64.8, CH | 67.0, CH | 74.8, CH | 71.7, CH | 120.8, CH |
12 | 76.0, C | 78.5, C | 77.6, C | 76.8, C | 75.4, C | 88.6, C | 88.5, C | 84.9, C | 141.0, C |
13 | 73.7, C | 27.7, CH | 35.2, CH | 26.7, CH | 86.5, C | 27.6, C | 35.0, C | 28.0, CH | 32.5, CH |
14 | 44.2, CH2 | 33.8, CH2 | 29.4, CH2 | 33.6, CH2 | 38.7, CH2 | 34.7, CH2 | 33.4, CH2 | 40.6, CH2 | 36.2, CH2 |
15 | 86.9, C | 87.4, C | 87.2, C | 80.7, C | 95.2, C | 78.0, C | 77.8, C | 76.7, C | 86.0, C |
16 | 84.4, C | 85.7, C | 84.8, C | 87.0, C | 90.0, C | 179.4, C | 184.6, C | 171.5, C | 199.4, C |
17 | 19.6, CH3 | 19.9, CH3 | 19.4, CH3 | 18.8, CH3 | 21.0, CH3 | 17.3, CH3 | 16.5, CH3 | 17.2, CH3 | 18.0, CH3 |
18 | 19.3, CH3 | 19.8, CH3 | 19.0, CH3 | 28.1, CH3 | 20.0, CH3 | 25.7, CH3 | 19.3, CH3 | 28.0, CH3 | 30.1, CH3 |
19 | 17.6, CH3 | 20.9, CH3 | 20.8, CH3 | 20.6, CH3 | 15.5, CH3 | 18.6, CH3 | 19.1, CH3 | 19.0, CH3 | 21.3, CH3 |
20 | 26.0, CH3 | 16.1, CH3 | 61.5, CH2 | 15.9, CH3 | 20.5, CH3 | 16.0, CH3 | 60.2, CH2 | 16.0, CH3 | 19.5, CH3 |
9-OCH3 | 56.9, CH3 |
Measured in DMSO-d6.
Measured in CD3OD.
Measured in CDCl3.