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. 2017 Aug 17;7:8670. doi: 10.1038/s41598-017-09261-7

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© The Author(s) 2017

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation orexceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Effect of adding the catalyst to the ultrafast transient absorption signal. Kinetic traces extracted at 795 nm from transient absorption spectroscopy measurements upon excitation at 405 nm for the complete system and in the absence of Ru NPs (hydrog en evolution catalyst). The instrument response function is ca. 200 fs.