Biochemical subtypes of C4 photosynthesis. Boxes represent the M and BS cells. Chloroplasts are in green and mitochondria brown. NADP-ME, NADP-dependent malic enzyme; PCK, phosphoenolpyruvate carboxykinase; NAD-ME, NAD-dependent malic enzyme; mMDH, mitochondrial malate dehydrogenase; CA, carbonic anhydrase; PEPC, phosphoenolpyuvate-carboxylase; PPDK, pyruvate,orthophosphate dikinase; AspAT, aspartate aminotransferase; RuBisCO, ribulose-1,5 bisphosphate carboxylase/oxygenase; AlaAT, alanine aminotransferase; CBB cycle, Calvin–Benson–Basham cycle; Asp, aspartate; Mal, malate; CO2, carbon dioxide; , bicarbonate; PEP, phosphoenolpyruvate; OAA, oxaloacetate; Pyr, pyruvate.