Skip to main content
. 2017 Jun 30;4(Pt 4):380–392. doi: 10.1107/S2052252517008326

Table 1. Metal–organic frameworks and the ionic liquids in which they were synthesized.

Metal–organic framework Ionic liquid Reference
     
§2: neither IL cation nor anion incorporation
Zn4(BTC)2(μ4-O)(H2O)2 [C2mim][Br] Xu et al. (2008c ▸)
[NBu4]2[Cu(BBTZ)2(Mo8O26)] [C2mim][Br] Fu et al. (2012 ▸, 2011 ▸)
(1-mim)Ni(BDC) [C3mim][Br] Hogben et al. (2006 ▸)
Zn3(BDC)3(1-mim)2 [C4mim][BF4] Wang et al. (2008 ▸)
Co[4,5-di(N-acetyl)­amino-2-methylimdiazo­late]2 [NEt4][2-methyl-4,5-di­cyano­imidazolate] Mondal et al. (2014 ▸)
Zn(C2O4)(C3N2H4) [C2mim][NTf2] Martins et al. (2010 ▸)
Zn(C3N2H3)2 [C2mim][NTf2] Martins et al. (2010 ▸)
Zn(OAc)(C3N2H3) [C2mim][NTf2] Martins et al. (2010 ▸)
Zn4(C3N2H3)8(C3N2H4) [C2mim][NTf2] Martins et al. (2010 ▸)
M 3[Fe(CN)6]2 (M = Ni, Cu, Co) [Cnmim][BF4], [Cnmim][Cl] (n = 2, 4, 10) Clavel et al. (2006 ▸); Larionova et al. (2008 ▸)
     
§3: IL cation incorporation/templating
[C2mim][Cd(BTC)] [C2mim][Br] Liao et al. (2006 ▸)
[Cnmim][Mn(BTC)] (n = 2 or 3) [C2mim][X] or [C3mim][X] (X = Cl, Br, I) Xu et al. (2013 ▸)
[C2mim]2[M 3(BTC)2(OAc)2] (M = Ni, Co) [C2mim][Br] Lin et al. (2006 ▸)
[C3mim]2[Co2(BTC)2(H2O)2] [C3mim][Br]–[C4mim][NTf2] mixture Wang et al. (2011 ▸)
[Cnmim][Ga(BDC)2] (n = 2 or 3) [Cnmim][Br] (n = 2 or 3) Li & Liu (2015 ▸)
[Cnmim]2[Co3(BDC)3Br2] (n = 2, 3, 4) [Cnmim][Br] (n = 2, 3, 4) Xu et al. (2014 ▸)
[C5mim]2[Co3(BDC)4] [C5mim][Br] Xu et al. (2014 ▸)
[Cnmim]2[Co3(BDC)3 X 2] (n = 2, 3, 4, 5; X = Cl, I) [Cnmim][X] (n = 2, 3, 4, 5; X = Cl, I) Zhang et al. (2016b ▸)
Co3(BDC)3(imidazole)2 [C2mim][Br], imidazole Wang et al. (2011 ▸)
[C4mim]2[Cd3(BDC)3Br2] [C4mim][Br] Liao & Huang (2006 ▸)
[C2mim]2[Zn3(BDC)3Cl2] [C2mim][Cl] Tapala et al. (2014 ▸)
[C4mim]2[Zn3(BDC)3Cl2] [C4mim][Cl] Tapala et al. (2014 ▸)
[Cnmim]2[Zn3(BDC)3 X 2] [Cnmim][X] (n = 2, 3, 4, 5; X = Cl, Br, I; except for the 3 ILs listed below Zhang et al. (2015 ▸)
Zn(BDC)(H2O) [C4mim][Cl], [C5mim][Cl], and [C5mim][Br] Zhang et al. (2015 ▸)
[C2mim]2[Sm2(BDC)3(H2BDC)Cl2] [C2mim][Br] Cao et al. (2014 ▸)
[C2mim][Ln2(μ2-Cl)(BDC)3] (Ln = Eu and Tb) [C2mim][Br] Cao et al. (2014 ▸)
[C2C2im][NaCu(BDC)2] [C2mim][BF4]–[C2mim][L-lactate] mixture Xiahou et al. (2013 ▸)
[C2mim]2[M 3(iso-BDC)4] (M = Mn, Co, Ni) [C2mim][Br] Chen et al. (2011 ▸)
[C2mim][La(5-NO2-iso-BDC)BrCl] [C2mim][Br] Chen et al. (2009 ▸)
[C2mim]2[La2Co(5-CH3-iso-BDC)2(OAc)2(CH3SO3)4] [C2mim][CH3SO3] Chen et al. (2009 ▸)
[C3′mim]2[Mg3(1,4-NDC)4(1-mim)2(H2O)2]·2H2O [C3′mim][Cl] Wu et al. (2011 ▸)
[C2mim]2[Zn3(BTetC)2]·2H2O [C2mim][Br] Ji et al. (2011 ▸)
[C4dmim][Mg3(OBA)3(HOBA)] [C4dmim][Br] Wu et al. (2012 ▸)
[C2mim][Co2(D-cam)2(OAc)] [C2mim][Br] Chen et al. (2008 ▸)
[C2mim][In(D-cam)2] [C2mim][ethyl sulfate] Zhang et al. (2008 ▸)
     
§4: IL anion incorporation or structure-directing effects
[C2mim]2[Co3(BTC)2(OAc)2] [C2mim][Br] Lin et al. (2007b ▸)
[C2mim][Co(BTC)] [C2mim][Br]–[C2mim][NTf2] mixture Lin et al. (2007b ▸)
[Co5(OH)2(OAc)8]·2H2O [C2mim][NTf2] Lin et al. (2007b ▸)
[C2mim][Co2(H2BTC)3(HBTC)(2,2′-bipy)2] [C2mim][NTf2], 2,2′-bi­pyridine Lin et al. (2007b ▸)
[Cd3F(ina)4(4-pic)3][BF4] [C4mim][BF4], 4-picoline Xie et al. (2012 ▸)
[Cd3F(ina)3(4,4′-bipy)2(4-pic)2][BF4]2·4,4′-bipy·2H2O [C4mim][BF4], 2,2′-bi­pyridine Xie et al. (2012 ▸)
[Cd3F(ina)3(4,4′-bipy)3][BF4]2·4,4′-bipy·2H2O [C4mim][BF4], 2,2′-bi­pyridine Xie et al. (2012 ▸)
[C2mim]2[Co(H2O)2(O2CCF2CF2CO2)2] [C2mim][Br]–[C2mim][NTf2] mixture Hulvey et al. (2009 ▸)
[C2mim]2[Co3(H2O)4(O2CCF2CF2CF2CO2)4] [C2mim][Br]–[C2mim][NTf2] mixture Hulvey et al. (2009 ▸)
[Cu(bpp)][BF4] [C4mim][BF4] Jin et al. (2002 ▸)
[Cu3(tpt)4][BF4]3·Inline graphictpt·5H2O [C4mim][BF4] Dybtsev et al. (2004 ▸)
[Cu2(1-tza)4]Br·H3O·Inline graphicH2O [C4mim][Br] Chen et al. (2014 ▸)
[Cu2(1-tza)4][BF4]·H3O·H2O [C4mim][BF4] Chen et al. (2014 ▸)
     
§5: IL cation and anion incorporation or combined structural control
[Zn3(BTC)2(H2O)2]·2H2O [C2mim][Br] Xu et al. (2007 ▸)
[C2mim][Zn(BTC)] [C2mim][Br] Xu et al. (2007 ▸)
[C3mim][Zn(BTC)] [C3mim][Br] Xu et al. (2007 ▸)
[C4mim]2[Zn4(BTC)3(OH)(H2O)3] [C4mim][Br] Xu et al. (2007 ▸)
[C5mim][Zn2(BTC)(OH)Br] [C5mim][Br] Xu et al. (2007 ▸)
[C4mim][Zn2(BTC)(OH)I] [C4mim][I] Xu et al. (2008b ▸)
[C2mim][Cd2(BTC)Cl2] [C2mim][Cl] Xu et al. (2008a ▸)
[C2mim][Cd(BTC)] [C2mim][Br] or [C2mim][I] Xu et al. (2008a ▸)
[C3mim][Cd(BTC)] [C3mim][X] (X = Cl, Br, or I) Xu et al. (2008a ▸)
[Cnmim]2[Ni3(BTC)2(OAc)2] (n = 2, 3, 4) [C2mim][X] (X = Cl, Br, I); [C3mim][X] (X = Cl, Br); [C4mim][Cl] Xu et al. (2009 ▸)
[Cnmim]2[Ni3(HBTC)4(H2O)2] (n = 3, 4) [C3mim][I]; [C4mim][X] (X = Br, I) Xu et al. (2009 ▸)
     
§6: other structure-directing effects
[C2mim][Br][Co2(HBTC)2(4,4′-bipy)3] [C2mim][Br], 4,4′-bi­pyridine Lin et al. (2008 ▸)
[C2mim][Br][Co(HBTC)(4,4′-bipy)2]·4,4′-bipy [C2mim][Br], 4,4′-bi­pyridine Lin et al. (2008 ▸)
[C2mim][Co(BTC)(imidazole)] [C2mim][Br], imidazole Lin et al. (2008 ▸)
[C2mim]2[Co(BTC)2(H2DABCO)] [C2mim][Br], DABCO Lin et al. (2008 ▸)
[K2(H2O)8][Cd3(BTetC)2] [C2mim][Br], KCl Ji et al. (2008 ▸)
[C4mim]2[Ni(HBTC)2(H2O)2] [C4mim][L-aspartate] Lin et al. (2007a ▸)
[C4mim]2[Ni(HBTC)2(H2O)2] (opposite chirality) [C4mim][D-aspartate] Lin et al. (2007a ▸)
[C2mim][NaCu(1,4-NDC)2] [C2mim][L-lactate]–[C2mim][BF4] mixture Liu et al. (2013 ▸)