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Reduction potentials (E1/2) as functions of solvent donor number. Redox couples: [(HL)2Fe6(CN)6]n−6 with n = 3/4 (red △, −13.5 mV/DN), 4/5 (red □, −7.7 mV/DN), and 5/6 (red ○, −4.8 mV/DN); {[(NH3)5Ru]2(pyz)}n+ with n = 4/5 (blue ■, −26.4 mV/DN) and 5/6 (blue ●, −26.3 mV/DN).
