Table 2.

Substrate scope for the Pd/Cu-catalyzed reductive cross coupling of monosubstituted olefins with aryl bromides.^[a]

^[a]All yields represent the average of isolated yields from two runs performed with 1 mmol of olefin.

^[b]Reaction was run with 1 mol% [Pd(cinnamyl)Cl]₂, 2.2 mol% BrettPhos, and 3 mol% P1.

^[c]Reaction run with 3.6 equiv of Me₂PhSiH.

^[d]Reaction was run at 0.25 M.

^[e]Reaction was run at 0.5 M.