Table 3.
Peak no. | Rt (min) | UV (nm) | Proposed | [M-H]- | MS/MS fragments | Identified | Reference |
---|---|---|---|---|---|---|---|
λmax | formula | (m/z) | (m/z) | compounds | |||
1 | 3.03 | 270 | C7H6O5 | 169.1450 | 125 | Gallic acid | Tang et al., 2016 |
2 | 3.48 | 325 | C9H8O4 | 179.1005 | 135 | Caffeic acid | Rameshkumar et al., 2013; Fang et al., 2015 |
3 | 4.02 | 320 | C16H18O9 | 353.1610 | 191, 179 | Chlorogenic acid | Rameshkumar et al., 2013 |
4 | 5.05 | 278 | C15H14O6 | 288.9121 | 123 | L-Epicatechin | Li et al., 2006 |
5 | 5.13 | 353, 252 | C21H20O12 | 463.0870 | 300 | Hyperoside | Chen et al., 2012; Deng et al., 2013 |
6 | 5.61 | 279 | C9H8O3 | 163.0396 | 119, 93 | p-Coumaric acid | Kumar et al., 2015; Kolniak-Ostek, 2016 |
7 | 5.85 | 354, 254 | C27H30O16 | 609.1456 | 301 | Rutin | Jiménez-Sánchez et al., 2016; Kolniak-Ostek, 2016 |
8 | 6.03 | 310, 290 | C10H10O4 | 193.0499 | 178 | Ferulic acid | Jeyadevi et al., 2013 |
9 | 6.09 | 354, 254 | C21H20O12 | 463.0870 | 301, 257, 179, 151 | Isoquercitrin | Simirgiotis et al., 2013 |
10 | 6.55 | 254 | C28H32O16 | 623.1619 | 315 | Narcissin | Jiménez-Sánchez et al., 2016 |
11 | 6.68 | 254 | C21H20O11 | 447.0916 | 357, 327, 297, 285 | Orientin | Li et al., 2006; Bilia et al., 2008 |
12 | 6.83 | 354, 254 | C22H22O12 | 477.1021 | 314 | Isorhamnetin-3-O-glucoside | Li et al., 2016 |
13 | 6.90 | 355, 254 | C21H20O11 | 447.0927 | 301, 179, 151 | Quercitrin | Simirgiotis et al., 2013 |
14 | 6.93 | 355 | C21H20O12 | 463.0870 | 301 | Quercetin-3-O-β-D-glucoside | Kolniak-Ostek, 2016 |
15 | 7.11 | 349, 255 | C21H20O11 | 447.0926 | 285 | Luteoloside | Fang et al., 2015 |
16 | 7.15 | 351 | C21H20O11 | 447.0939 | 161 | Kaempferol-3-O-galactoside | Guo and Zhang, 2015 |
17 | 8.48 | 360, 256 | C15H10O7 | 301.0349 | 179, 151, 107 | Quercetin | Kumar et al., 2015; Jiménez-Sánchez et al., 2016 |
18 | 8.85 | 340, 258 | C15H10O5 | 269.0442 | 225, 117 | Apigenin | Lai et al., 2016 |
19 | 9.67 | 350, 254 | C15H10O6 | 285.0395 | 257 | Luteolin | Sánchez-Vioque et al., 2013 |
20 | 9.70 | 287, 230 | C15H10O6 | 285.0395 | 151, 133 | Kaempferol | Kumar et al., 2015 |
21 | 9.91 | 354, 265 | C16H12O7 | 315.0502 | 300, 179, 151 | Isorhamnetin | Simirgiotis et al., 2013 |