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. 2017 Aug 24;8:1474. doi: 10.3389/fpls.2017.01474

Table 3.

The components identified by UPLC-Q-TOF-MS/MS in A. roxburghii.

Peak no. Rt (min) UV (nm) Proposed [M-H]- MS/MS fragments Identified Reference
λmax formula (m/z) (m/z) compounds
1 3.03 270 C7H6O5 169.1450 125 Gallic acid Tang et al., 2016
2 3.48 325 C9H8O4 179.1005 135 Caffeic acid Rameshkumar et al., 2013; Fang et al., 2015
3 4.02 320 C16H18O9 353.1610 191, 179 Chlorogenic acid Rameshkumar et al., 2013
4 5.05 278 C15H14O6 288.9121 123 L-Epicatechin Li et al., 2006
5 5.13 353, 252 C21H20O12 463.0870 300 Hyperoside Chen et al., 2012; Deng et al., 2013
6 5.61 279 C9H8O3 163.0396 119, 93 p-Coumaric acid Kumar et al., 2015; Kolniak-Ostek, 2016
7 5.85 354, 254 C27H30O16 609.1456 301 Rutin Jiménez-Sánchez et al., 2016; Kolniak-Ostek, 2016
8 6.03 310, 290 C10H10O4 193.0499 178 Ferulic acid Jeyadevi et al., 2013
9 6.09 354, 254 C21H20O12 463.0870 301, 257, 179, 151 Isoquercitrin Simirgiotis et al., 2013
10 6.55 254 C28H32O16 623.1619 315 Narcissin Jiménez-Sánchez et al., 2016
11 6.68 254 C21H20O11 447.0916 357, 327, 297, 285 Orientin Li et al., 2006; Bilia et al., 2008
12 6.83 354, 254 C22H22O12 477.1021 314 Isorhamnetin-3-O-glucoside Li et al., 2016
13 6.90 355, 254 C21H20O11 447.0927 301, 179, 151 Quercitrin Simirgiotis et al., 2013
14 6.93 355 C21H20O12 463.0870 301 Quercetin-3-O-β-D-glucoside Kolniak-Ostek, 2016
15 7.11 349, 255 C21H20O11 447.0926 285 Luteoloside Fang et al., 2015
16 7.15 351 C21H20O11 447.0939 161 Kaempferol-3-O-galactoside Guo and Zhang, 2015
17 8.48 360, 256 C15H10O7 301.0349 179, 151, 107 Quercetin Kumar et al., 2015; Jiménez-Sánchez et al., 2016
18 8.85 340, 258 C15H10O5 269.0442 225, 117 Apigenin Lai et al., 2016
19 9.67 350, 254 C15H10O6 285.0395 257 Luteolin Sánchez-Vioque et al., 2013
20 9.70 287, 230 C15H10O6 285.0395 151, 133 Kaempferol Kumar et al., 2015
21 9.91 354, 265 C16H12O7 315.0502 300, 179, 151 Isorhamnetin Simirgiotis et al., 2013