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. 2017 Aug 29;7:9800. doi: 10.1038/s41598-017-10314-0

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© The Author(s) 2017

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fluorescence emission spectra of BSA (10.5 μM) in the presence of: [CoD]⁻ – 1 (A), 4 (B), 7 (C) and 10 (D) in 0.10 M sodium bicarbonate (pH 8.4) with 2% DMSO, λ _ex = 280 nm, 298 K. The concentration of 1 and 4 was 0 to 10.5 μM with 1.05 μM intervals; the concentration of 7 and 10 was 0 to 105 μM with 17.5 μM intervals. Detailed molar excess of boron cluster is described in the legend. Inset: Stern-Volmer plots for BSA – boron cluster complexes.