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Molecular structure of Zr3 at 150 K. Thermal ellipsoids set at 30 % probability, and non‐phosphorus‐bound hydrogen atoms, minor disorder components, and the potassium bis(B15C5) cation component, are omitted for clarity. The Zr⋅⋅⋅HP interaction is represented by a dashed line. Selected bond lengths [Å] and angles [°]: Zr1−P1 2.4723(17), Zr1−N1 2.135(5), Zr1−N2 2.109(5), Zr1−N3 2.127(5), Zr1−N4 2.586(4), Zr⋅⋅⋅HP 2.322(19); Zr1−P1−H1 66.7(8).
