Figure 2.

Schematic representation of the application of NMR methods to probe different time scales of motions and self‐organisation in supramolecular materials at different length scales. While the rigid fibres can be studied by ¹H‐¹³C CP/MAS solid‐state NMR experiments, structure and dynamics of mobile molecules were characterised by spectral variations and ¹H T ₁ measurements from solution‐state NMR experiments. Molecules at gel/solution interfaces with intermediate frequencies of motion can be assessed using HR‐MAS NMR experiments, and their dynamics of exchange studied by solution‐state STD NMR.