Table 2.
Diffusion coefficient [μm2/s] | ||||
---|---|---|---|---|
Radius [nm] | ϕ | D S | D L | |
50 | 10−3 | a | 0.22 ± 0.01 | |
r = ϕ L/ϕ s | 1000 | 10−5 | 4.1 ± 0.1 | a |
0.003 | 50 | 10−3 | 4.3 ± 0.3b | 0.20 ± 0.01 |
1000 | 3 × 10−6 | |||
0.01 | 50 | 10−3 | 4.0 ± 0.2b | 0.19 ± 0.01 |
1000 | 1 × 10−5 | |||
0.03 | 50 | 10−3 | 4.4 ± 0.4b | 0.20 ± 0.01 |
1000 | 3 × 10−5 |
Error bars are numerical uncertainty from fitting functions. Stokes-Einstein diffusivities are 4.3 and 0.21 μm2/s for small and large particles, respectively
a measurements made on unary samples lacking this particle population
b calculated from the experimentally-measured large-particle diffusivity using the globally-fit size ratio f r