Table 1. Hydration effects of Co(NH3)63+ binding to CT DNA in 5 mM CsCl, 0.2 mM Cs HEPES, pH 7.3, at 20°C.
DNA |
ΔA (cm3 mol–1) |
ΔV (cm3 mol–1) |
Δκ × 104 (cm3 mol–1 bar–1) |
160 bp | 30.6 ± 2 | 9.3 ± 1.5 | 35.5 ± 3.5 |
3–8 kb | 26.5 ± 2 | 8.4 ± 1.5 | 31.1 ± 3.5 |