Table 1.
No. | 1 | 2 | ||||||
---|---|---|---|---|---|---|---|---|
13C | 1H (J in Hz) | 13C | 1H (J in Hz) | |||||
1 | 167.0 | s | - | - | 166.5 | s | - | - |
2 | 119.0 | s | - | - | 128.2 | s | - | - |
3 | 106.0 | d | - | 6.38 brs | 140.0 | d | - | 6.63 brd (6.7) |
4 | 156.4 | s | - | - | 23.8 | t | a | 2.34 m |
- | - | - | - | - | - | - | b | 2.21 ddd (3.1, 6.7, 17.7) |
5 | 38.1 | t | - | 3.28 s (2H) | 81.9 | d | - | 4.30 dd (3.1, 12.9) |
6 | 130.9 | s | - | - | 38.9 | s | - | - |
7 | 127.2 | d | - | 5.24 m | 31.8 | t | α | 1.56 m |
- | - | - | - | - | - | - | β | 1.30 m |
8 | 26.3 | t | - | 2.16 m (2H) | 17.4 | t | - | 1.51 m (2H) |
9 | 39.2 | t | - | 2.06 m (2H) | 37.8 | t | α | 0.97 dt (3.1, 12.6) |
- | - | - | - | - | - | - | β | 1.67 m |
10 | 139.7 | s | - | - | 38.9 | s | - | - |
11 | 124.9 | d | - | 5.24 m | 46.6 | d | - | 1.73 dd (2.6, 11.3) |
12 | 75.9 | d | - | 4.56 dt (8.4, 5.9) | 17.5 | t | α | 1.55 m |
- | - | - | - | - | - | - | β | 1.47 m |
13 | 39.4 | t | a | 2.58 dd (5.9, 15.0) | 41.6 | t | α | 1.65 m |
- | - | - | b | 2.23 m | - | - | β | 1.70 m |
14 | 139.8 | s | - | - | 73.0 | s | - | - |
15 | 119.2 | d | - | 5.33 m | 58.8 | d | - | 1.05 brs |
16 | 29.9 | t | - | 2.16 m (2H) | 26.0 | t | a | 1.68 m |
- | - | - | - | - | - | - | b | 1.54 m |
17 | 24.6 | t | - | 2.48 t (7.5) (2H) | 28.4 | t | a | 2.44 m |
- | - | - | - | - | - | - | b | 2.39 m |
18 | 124.5 | s | - | - | 125.4 | s | - | - |
19 | 110.9 | d | - | 6.26 brs | 110.9 | d | - | 6.29 brs |
20 | 142.7 | d | - | 7.34 brs | 142.6 | d | - | 7.35 brt (1.5) |
21 | 138.9 | d | - | 7.21 brs | 138.6 | d | - | 7.25 brs |
22 | 68.3 | t | a | 4.39 d (13.0) | 30.5 | q | - | 1.18 s |
- | - | - | b | 4.20 d (13.0) | - | - | - | - |
23 | 16.7 | q | - | 1.70 brs | 15.9 | q | - | 1.03 s |
24 | 15.9 | q | - | 1.60 brs | 17.4 | q | - | 0.87 s |
25 | 147.7 | d | - | 7.96 brs | 16.9 | q | - | 1.92 s |