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. 2017 Jul 19;23(44):10496–10500. doi: 10.1002/chem.201702767

Table 1.

13C (red/white dots) SABRE signal enhancement (ϵ) over the corresponding thermal measurement at 9.4 T after transfer at the indicated field (G), net polarization (P) and T 1 and T S lifetimes (s) of substrate 18 in high field (HF: 9.4 T) and low field (LF: ≈10 mT). The J‐coupling between the 13C spin‐pair was found to be about 58.5±2.0 Hz in all cases. The ΔJ CH values for Type‐1 substrates, and the chemical shift difference (Δv) for Type‐2 substrates are noted.

Agent Substrate structure Enhancement (ϵ), transfer field, net polarization level P [%] Lifetime [s] ΔJ CH* or Δv@9.4 T [Hz]
1 graphic file with name CHEM-23-10496-g006.jpg ϵ: 2500±300 @30 G P≈2.0 T 1: 9.7±0.3 T S(HF): 75±5.5 T S(LF): 115±12 3.1±0.2*
2 graphic file with name CHEM-23-10496-g007.jpg ϵ: 1600±280 @150 G P≈1.3 T 1: 12.4±0.9 T S(HF/LF): – 2 J CD≈0.4*
3 graphic file with name CHEM-23-10496-g008.jpg ϵ: 600±50 @20 mG P≈0.5 T 1: 16.0±1.5 T S(HF/LF): No access 0
4 graphic file with name CHEM-23-10496-g009.jpg ϵ: 1600±300 @150 G P≈1.3 T 1: 10.2±0.6 T S(HF): 22±3.0 T S(LF): 28±6.5 11.0±0.1
5 graphic file with name CHEM-23-10496-g010.jpg ϵ: 550±50 @5 mG P≈0.45 T 1: 15.5±1.2 T S(HF): 90±3.0 T S(LF): 165±18 10.4±0.1
6 graphic file with name CHEM-23-10496-g011.jpg ϵ: 350±40 @10 mG P≈0.35 T 1: 10.4±0.3 T S(HF): 115±5.5 T S(LF): 148±20 14.5±0.4
7 graphic file with name CHEM-23-10496-g012.jpg ϵ: 600±50 @1 mG P≈0.50 T 1: 15.2±0.3 T S(HF): 145±6.0 T S(LF): 186±18 4.4±0.3
8 graphic file with name CHEM-23-10496-g013.jpg ϵ: 800±150 @10 mG P≈0.65 T 1: 7.5±0.5 T S(HF): <5 T S(LF): 45±6.0 78.8±0.5