Table 1. Chemical shift assignments in p.p.m. for the GTAC region of the 2.5 mM sample of 1.
Base |
H1′ |
H2′ |
H2″ |
H3′ |
H4′ |
H8/H6 |
H2/H5/Me |
NH imino |
NH2 |
G6 α | 5.67 | 2.41 | 2.42 | 4.89 | 4.29 | 7.52 | 12.73 | ||
G6 β | 5.67 | 2.41 | 2.42 | 4.92 | 4.29 | 7.55 | |||
Abasic α | 5.26 | 1.96 | 1.83 | 4.49 | 4.38 | ||||
Abasic β | 5.33 | 1.87 | 2.06 | 4.42 | 4.05 | ||||
A8 | 6.35 | 2.81 | 2.96 | 5.00 | 4.48 | 8.39 | 7.70 | ||
C9 | 5.81 | 1.90 | 2.45 | 4.72 | 4.22 | 7.31 | 5.26 | 6.73 | |
8.07 | |||||||||
G18 α | 5.79 | 2.41 | 2.57 | 4.87 | 4.36 | 7.55 | 12.66 | ||
G18 β | 5.79 | 2.40 | 2.56 | 4.87 | 4.36 | 7.53 | 12.66 | ||
T19 α | 5.74 | 1.95 | 2.29 | 4.72 | 4.21 | 7.05 | 1.23 | 14.16 | |
T19 β | 5.73 | 1.94 | 2.26 | 4.70 | 4.21 | 7.02 | 1.18 | 14.16 | |
A20 α | 6.10 | 2.52 | 2.68 | 4.92 | 4.35 | 8.14 | 7.37 | ||
A20 β | 6.11 | 2.51 | 2.68 | 4.92 | 4.35 | 8.16 | 7.37 | ||
C21 α | 5.91 | 2.23 | 2.51 | 4.76 | 4.28 | 7.67 | 5.67 | ||
C21 β | 5.91 | 2.22 | 2.51 | 4.76 | 4.26 | 7.67 | 5.67 |