Skip to main content
. Author manuscript; available in PMC: 2017 Sep 8.
Published in final edited form as: Angew Chem Int Ed Engl. 2014 Jul 14;53(36):9637–9639. doi: 10.1002/anie.201405594

Table 2.

Metathesis reactions of iodonium triflate 5.

graphic file with name nihms898870u3.jpg
entry Ar’ time ratio 6:4:5:(other)[b] yield[c]
a Ph 15 h 13.9[d]:1.0:(−)[e] 51
b 4-MeC6H4 15 h 6.0:35.7:1.0:(−)[e] 59
c 4-MeOC6H4 15 h 2.3:2.2:1.0:(−)[f] 80
d 1-naphthyl 24 h 6.6:1.8:1.0:(−)[e] 35
[a], [b], [c]

Same as for Table 1.

[d]

Compounds 7 and 4 are identical in this case.

[e]

Other products — if at all detectable — were present in insignificant amounts.

[f]

A trace amount of Ph2IOTf, too small to be measured accurately and perhaps arising as per ref. 1, was apparent by 1H-NMR and MS.