Table 3. Selected structural data of compounds 17 a .
Compound | 17a | 17b | 17c |
R | Ph | Mes | t Bu |
B1–P1 | 2.052(2) | 2.085(2) | 2.069(2) |
P1–C1 | 1.835(2) | 1.834(2) | 1.827(2) |
C1–C2 | 1.513(2) | 1.509(3) | 1.504(3) |
C2–C3 | 1.334(3) | 1.324(3) | 1.321(3) |
C3–C4 | 1.499(3) | 1.497(3) | 1.497(3) |
B1–C4 | 1.649(2) | 1.643(3) | 1.649(3) |
C1–P1–B1 | 104.7(1) | 101.9(1) | 98.3(1) |
C4–B1–P1 | 101.9(1) | 97.0(1) | 103.1(1) |
P1–B1–C4–C3 | –49.9(2) | 67.8(2) | 25.9(2) |
B1–P1–C1–C2 | 48.8(1) | 17.8(2) | 57.3(2) |
∑P1CCC | 317.1 | 316.4 | 317.2 |
∑B1CCC | 338.2 | 332.8 | 326.4 |
aBond lengths in Å, angles in deg.