Table 4. Selected NMR data of the compounds 17 a .
Compound | 17a | 17b | 17c |
R | Ph | Mes | t Bu |
31P | 1.3 | 1.7 | 15.0 |
11B | –13.6 | –8.1 | –13.9 |
C1 | 27.7 | 31.6 | 21.5 |
C2 | 125.2 | 128.3 | 124.7 |
C3 | 132.1 | 128.4 | 131.1 |
C4 | 21.7 | 19.5 | 27.3 |
1-H | 2.98 | 3.98/2.71 | 2.38 |
3-H | 6.09 | 5.46 | 5.78 |
4-H | 2.13 | 2.23/1.71 | 2.03 |
19F (o) | –129.2 | –125.5/–127.4/–128.6/–131.5 | –124.0/–125.5/–129.8/–132.1 |
19F (p) | –159.3 | –158.0/–160.9 | –157.4/–160.7 |
19F (m) | –165.0 | –164.7 (2F)/–165.2/–165.8 | –163.0/–163.8/–164.0/–165.0 |
aIn CD2Cl2, chemical shifts in ppm, δ-scale.