Table 6. Chemical Potentials of Reactants and Reaction Products for Different Reactions of the Lennard-Jones System at Different Pressures Obtained with Serial Rx/CFCa.
| Reaction | P | ∑reactants νiμiexcess | ∑reactants νiμitot | ∑products νiμiexcess | ∑products νiμitot |
|---|---|---|---|---|---|
| 0.3 | –0.344(9) | 7.036(9) | –0.344(6) | 7.036(6) | |
| A ⇌ B | 1.0 | 0.07(1) | 9.42(1) | 0.066(6) | 9.421(6) |
| 3.0 | 2.73(1) | 12.95(1) | 2.727(6) | 12.953(6) | |
| 5.0 | 5.23(1) | 15.74(1) | 5.23(2) | 15.73(1) | |
| 0.3 | –0.265(8) | 7.101(8) | –0.133(6) | 7.101(6) | |
| A ⇌ C | 1.0 | 0.25(1) | 9.66(1) | 0.79(1) | 9.67(1) |
| 3.0 | 2.887(6) | 13.541(6) | 4.32(1) | 13.53(1) | |
| 5.0 | 5.35(2) | 16.53(2) | 7.51(2) | 16.52(2) | |
| 0.3 | –0.34(1) | 6.13(1) | –0.68(1) | 6.12(1) | |
| A ⇌ 2D | 1.0 | 0.07(1) | 9.49(1) | 0.13(1) | 9.48(1) |
| 3.0 | 2.73(1) | 13.79(1) | 5.43(4) | 13.74(2) | |
| 5.0 | 5.23(2) | 16.84(2) | 10.45(3) | 16.74(2) | |
| 0.3 | –0.240(9) | 6.253(8) | –0.205(9) | 6.245(9) | |
| A ⇌ 2E | 1.0 | 0.247(8) | 9.791(7) | 1.553(9) | 9.772(9) |
| 3.0 | 2.81(1) | 14.08(1) | 8.45(3) | 13.98(1) | |
| 5.0 | 5.25(3) | 17.02(3) | 14.78(8) | 16.67(6) | |
| 0.3 | –0.340(8) | 4.319(8) | –0.68(1) | 4.32(1) | |
| A ⇌ D + F | 1.0 | 0.07(1) | 8.30(2) | 0.13(1) | 8.29(1) |
| 3.0 | 2.724(9) | 13.246(6) | 5.44(2) | 13.213(8) | |
| 5.0 | 5.23(1) | 16.57(1) | 10.45(4) | 16.52(2) | |
| 0.3 | –0.270(7) | 4.418(7) | –0.41(1) | 4.43(1) | |
| A ⇌ D + E | 1.0 | 0.220(9) | 8.578(9) | 0.96(1) | 8.57(1) |
| 3.0 | 2.809(9) | 13.573(9) | 7.04(2) | 13.528(6) | |
| 5.0 | 5.27(2) | 16.80(2) | 12.69(6) | 16.69(3) |