Table 4.
Entry | Nitro compound | Product | a Conversion % | b Yield % |
---|---|---|---|---|
1 | >99 | 96 | ||
2 | >99 | 96 | ||
3 | >99 | 95 | ||
4 | >96 | 92c | ||
5 | >97 | 96 | ||
6 | 93 | 92 | ||
7 | >42 | 37c | ||
8 | >99 | 98 | ||
9 | >97 | 94c | ||
10 | 99 | 96d | ||
11 | 99 | 96 | ||
12 | 99 | 96 | ||
13 | 99 | 96e | ||
14 | 99 | 95f | ||
15 | 99 | 95c |
a Reaction conditions: Nitrobenzene (0.5 mmol), Hydrazine hydrate (100 μL), Fe3O4 (30 mg), EtOH (1.5 mL), temperature (90 °C), time (15 min).
bDetermined by GC using dodecane as an internal standard.
creaction time (25 min),
dreaction time (20 min),
ereaction time (22 min),
fisolated yield.