Skip to main content
. 2017 Sep 14;7:11585. doi: 10.1038/s41598-017-09477-7

Table 4.

Catalytic reduction of nitro compoundsa.

graphic file with name 41598_2017_9477_Figd_HTML.gif
Entry Nitro compound Product a Conversion % b Yield %
1 graphic file with name 41598_2017_9477_Fige_HTML.gif graphic file with name 41598_2017_9477_Figt_HTML.gif >99 96
2 graphic file with name 41598_2017_9477_Figf_HTML.gif graphic file with name 41598_2017_9477_Figu_HTML.gif >99 96
3 graphic file with name 41598_2017_9477_Figg_HTML.gif graphic file with name 41598_2017_9477_Figv_HTML.gif >99 95
4 graphic file with name 41598_2017_9477_Figh_HTML.gif graphic file with name 41598_2017_9477_Figw_HTML.gif >96 92c
5 graphic file with name 41598_2017_9477_Figi_HTML.gif graphic file with name 41598_2017_9477_Figx_HTML.gif >97 96
6 graphic file with name 41598_2017_9477_Figj_HTML.gif graphic file with name 41598_2017_9477_Figy_HTML.gif 93 92
7 graphic file with name 41598_2017_9477_Figk_HTML.gif graphic file with name 41598_2017_9477_Figz_HTML.gif >42 37c
8 graphic file with name 41598_2017_9477_Figl_HTML.gif graphic file with name 41598_2017_9477_Figaa_HTML.gif >99 98
9 graphic file with name 41598_2017_9477_Figm_HTML.gif graphic file with name 41598_2017_9477_Figab_HTML.gif >97 94c
10 graphic file with name 41598_2017_9477_Fign_HTML.gif graphic file with name 41598_2017_9477_Figac_HTML.gif 99 96d
11 graphic file with name 41598_2017_9477_Figo_HTML.gif graphic file with name 41598_2017_9477_Figad_HTML.gif 99 96
12 graphic file with name 41598_2017_9477_Figp_HTML.gif graphic file with name 41598_2017_9477_Figae_HTML.gif 99 96
13 graphic file with name 41598_2017_9477_Figq_HTML.gif graphic file with name 41598_2017_9477_Figaf_HTML.gif 99 96e
14 graphic file with name 41598_2017_9477_Figr_HTML.gif graphic file with name 41598_2017_9477_Figag_HTML.gif 99 95f
15 graphic file with name 41598_2017_9477_Figs_HTML.gif graphic file with name 41598_2017_9477_Figah_HTML.gif 99 95c

a Reaction conditions: Nitrobenzene (0.5 mmol), Hydrazine hydrate (100 μL), Fe3O4 (30 mg), EtOH (1.5 mL), temperature (90 °C), time (15 min).

bDetermined by GC using dodecane as an internal standard.

creaction time (25 min),

dreaction time (20 min),

ereaction time (22 min),

fisolated yield.