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. 2017 Aug 16;10(17):3317–3332. doi: 10.1002/cssc.201701058

Table 3.

Rh‐catalyzed C−H carboxylation of simple arenes. Inline graphic

Reactant T [°C] Main product TON [%] Regioselectiviy [α:β:γ]
graphic file with name CSSC-10-3317-g051.jpg   graphic file with name CSSC-10-3317-g052.jpg    
84 a 85 91 a 37 –
graphic file with name CSSC-10-3317-g053.jpg   graphic file with name CSSC-10-3317-g054.jpg    
84 b 120 91 b 18 17:57:26
graphic file with name CSSC-10-3317-g055.jpg   graphic file with name CSSC-10-3317-g056.jpg    
84 c 145 91 c 39 23:54:23
graphic file with name CSSC-10-3317-g057.jpg   graphic file with name CSSC-10-3317-g058.jpg    
84 d 85 91 d 39 59:29:12
graphic file with name CSSC-10-3317-g059.jpg   graphic file with name CSSC-10-3317-g060.jpg    
84 e 145 91 e 12 100:0:0
graphic file with name CSSC-10-3317-g061.jpg   graphic file with name CSSC-10-3317-g062.jpg    
84 f 145 91 f 21 86:14:0
graphic file with name CSSC-10-3317-g063.jpg   graphic file with name CSSC-10-3317-g064.jpg    
84 g 145 91 g 60 –