Figure 3.
Oxidation of DTTred with H2O2 in the presence of compounds 10, SLC-0111, and 22. Reaction conditions: [DTTred]0 = 0.14 mM, [H2O2]0 = 0.14 mM, [catalyst] = 0.014 mM, CD3OD = 1.1 mL. 1H NMR spectra were measured at variable reaction time at 25 °C. The relative populations of DTTred and DTTox were determined by integration of the 1H NMR signals. In the control experiment the reaction was run with no catalyst. Reported are the mean ± SD values of three separate experiments.