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. Author manuscript; available in PMC: 2018 Jun 14.
Published in final edited form as: J Am Chem Soc. 2017 Jun 6;139(23):7958–7973. doi: 10.1021/jacs.7b03292

Table 2. Summary of Kinetics Data Using the Reaction Conditions Given in Scheme 1.

{1 + p-OMe-PhOH} kinetics data (50 equiv, –70 °C)a
kobs(p-OMe-PhOH) (s−1) 4.18 (0.2) × 10−4
kobs(p-OMe-PhOD) (s−1) 2.41 (0.4) × 10−4
KIE (kH/kD) 1.7 (0.3)
ΔGǂ (kcal/mol) 14.9 (0.1)
a

Error margins are noted in parentheses. Data for individual trials are given in Table S4.