Table 2. The asymmetric cyclopropanation of alkenes with t-BFDA by [Co(P2)] a , b , c .
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aCarried out in one-portion under N2 with [olefin] = 0.20 M.
bIsolated yields.
cee of major (E)-diastereomer determined by chiral HPLC.
dee determined upon derivatization.
eResults in the parentheses were obtained for the reaction performed on a 1.0 mmol scale.
fAbsolute configuration determined by X-ray diffraction as [1R,2S].
g5 equiv. olefin.
hee determined by chiral GC.
iNeat condition.