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. Author manuscript; available in PMC: 2017 Sep 23.
Published in final edited form as: J Am Chem Soc. 2016 Jun 29;138(27):8324–8327. doi: 10.1021/jacs.6b02469

Figure 2.

Figure 2

Reaction of ammonia with 8-formyl-lumiflavin (4) to form 8-amino-lumiflavin (5). This reaction is a model system for the remarkable methyl group replacement that occurs during roseoflavin biosynthesis.