Scheme 3. Comparison of NPA charges for the Fe(ii) and Mn(i) pincer complexes and computational free energies ΔG o for the CO2 insertion into the metal–H bond to yield the κ1-O formate complexes according to Scheme 2.
Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.