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. 2017 Jul 17;8(9):6493–6498. doi: 10.1039/c7sc02482g

Table 2. Rate constants and turnover frequencies determined from CV measurements a .

Substrate k cat (M–1 s–1) TOF b (s–1)
1@GC p-AnOH, 5a 460 37 ± 0.7
1 p-AnOH, 5a 105 8.4 ± 1.4
TAI d p-AnOH, 5a 75 5.9
1@GC BMMB, 6a 575 46 ± 0.7
1 BMMB, 6a 4.1 0.33 ± 0.03
TAI d BMMB, 6a c c

aResults are average of at least 3 trials.

bTOF calculated from k cat using eqn (4) and the concentration of substrate in CV experiments (80 mM).

cValue not reported in literature and cannot be calculated from available information.

dValues for TAI taken from literature. Ref. 16.