Table 2. Comparison of cubane redox potentials in aprotic solvent and water.
Cubane | E 1 (V), aprotic solvent | E 1 (V), water a | ΔE 1 | Reference |
4OAc-4COOEtpy | 0.48 | 1.00 | 0.52 | 20 and 23 |
NBA,3OAc-4py | 0.34 | 0.89 | 0.55 | |
4OAc-4py | 0.28 | 0.85 | 0.57 | |
4OAc-4Mepy | 0.27 | 0.84 | 0.57 | 20 |
4OAc-4DMAP | 0.11 | 0.68 | 0.57 |
aPotential versus Fc/Fc+.24