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. 2017 Apr 7;8(6):4274–4284. doi: 10.1039/c7sc00627f

Table 2. Comparison of cubane redox potentials in aprotic solvent and water.

Cubane E 1 (V), aprotic solvent E 1 (V), water a ΔE 1 Reference
4OAc-4COOEtpy 0.48 1.00 0.52 20 and 23
NBA,3OAc-4py 0.34 0.89 0.55
4OAc-4py 0.28 0.85 0.57
4OAc-4Mepy 0.27 0.84 0.57 20
4OAc-4DMAP 0.11 0.68 0.57

aPotential versus Fc/Fc+.24