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Attack trajectory of H2O on oxidized dOG determines the stereochemistry of dSp. (A) The re vs. si faces of dOG when base paired with dC in a duplex. (B) Attack trajectory of H2O on oxidized dOG determines the stereochemistry of the intermediate 5-HO-dOG that undergoes stereospecific 1,2-acyl shift to dSp.
