Table 1. Catalyst optimization for the synthesis of linear poly(glycerol sebacate) a .
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Entry | Catalyst | % 1,2 b | % triacylglycerol b | M n c (kDa) | Đ c |
1 | None | 11 | 5 | 8.7 | 1.7 |
2 | 1a | 7 | <1 | 12.5 | 1.3 |
3 | 1b | 6 | <1 | 11.9 | 1.2 |
4 | 1c | 6 | <1 | 19.2 | 1.2 |
aBased on analysis of polymers obtained after an aqueous workup, without further purification or fractionation.
bDetermined by quantitative 13C NMR spectroscopy.
cDetermined by GPC.